622 research outputs found
Localized Induction Equation for Stretched Vortex Filament
We study numerically the motion of the stretched vortex filaments by using
the localized induction equation with the stretch and that without the stretch.Comment: Published in SIGMA (Symmetry, Integrability and Geometry: Methods and
Applications) at http://www.emis.de/journals/SIGMA
Calculations of Cotton Effects in the Vacuum UV Region for Aldonic Acid 1,4-Lactones and Interpretations of Hudson\u27s Lactone Rule
A graphic method of Drude equation was applied to a series
of aldonic acid 1,4-lactones 1-7 to investigate possible Cotton
effects below 200nm. The calculation shows three bands at 220nm,
170 nm and 130 nm to reflect the stereochemistries at C-2, C-4
and rtng conformations and vicinal OH at C-3 and C-4, respectively.
The sum of the rotational contributions at 589 nm of these
bands explained the applicability of Hudson\u27s lactone rule in sugar
lactones
Calculations of Cotton Effects in the Vacuum UV Region for Chilar v-Lactones. Correlation with the Absolute Stereochemistry
A graphic method of Drude equations was applied to calculate
the Cotton effects below 180 nm region for various types of aand/
er y-substituted-y-lactones 1-10. The Cotton effects at ca.
170 nm were found to reflect the stereochemistry at C-2 (negative
for f3 and positive for a) and C-4 (positive for f3 and negative
for a) as well as the ring conformation (positive for E3
and negative for 3E) of which rotational contributions at 589 nm
were suggested as the origin of Hudson\u27s lactone rule
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